ISO/TR 16178:2021
Footwear — Critical substances potentially present in footwear and footwear components — Lists of critical chemical substances
This document defines lists of critical chemical substances potentially present in footwear and footwear components.
This document describes the critical chemical substances, their potential risks of nocuousness, in which materials they could be found, and which test method(s) can be used to quantify them.
The test methods listed indicate the state of the art. For some substances, a test method is not available.
This document is applicable to any kind of footwear and footwear components.
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Foreword
1 Scope
2 Normative references
3 Terms and definitions
4 Presence of chemicals in footwear materials
5 Critical substances potentially present in footwear and footwear components
5.1 Acrylonitrile
5.1.1 General
5.1.2 Potential risks
5.1.3 Test methods
5.2 Alkylphenols and Alkylphenol ethoxylates (NP, OP, NPEO, OPEO)
5.2.1 General
5.2.2 Potential risks
5.2.3 Test methods
5.3 Aromatic amines
5.3.1 General
5.3.2 Potential risks
5.3.3 Test methods
5.4 Benzene
5.4.1 General
5.4.2 Potential risks
5.4.3 Test methods
5.5 Biocides
5.5.1 Orthophenylphenol
5.5.2 2-(thiocyanatomethylthio)-1,3-benzothiazole (TCMTB)
5.5.3 2-octylisothiazol-3(2H)-one (OIT)
5.5.4 4-Chloro-3-methylphenol (CMK)
5.5.5 Triclosan
5.6 Bisphenol
5.6.1 General
5.6.2 Potential risks
5.6.3 Test methods
5.7 Cadmium – Cd
5.8 Chlorinated paraffins
5.8.1 General
5.8.2 Potential risks
5.8.3 Test methods
5.9 Chlorobenzenes and chlorotoluenes
5.9.1 General
5.9.2 Potential risks
5.9.3 Test methods
5.10 Chromium and Chromium VI
5.11 Colophony
5.11.1 General
5.11.2 Potential risks
5.11.3 Test methods
5.12 Dimethylformamide
5.12.1 General
5.12.2 Potential risks
5.12.3 Test methods
5.13 Dimethylfumarate (DMFu)
5.13.1 General
5.13.2 Potential risks
5.13.3 Test methods
5.14 Disperses dyes
5.14.1 General
5.14.2 Potential risks
5.14.3 Test methods
5.15 Flame retardants
5.15.1 General
5.15.2 Potential risks
5.15.3 Test methods
5.16 Formaldehyde
5.16.1 General
5.16.2 Potential risks
5.16.3 Test methods
5.17 Heavy metals
5.17.1 General
5.17.2 List of heavy metals
5.17.3 Potential risks
5.17.4 Test methods
5.17.5 Special cases
5.18 Mercaptobenzothiazole
5.18.1 General
5.18.2 Potential risks
5.18.3 Test methods
5.19 N-ethylphenylamine
5.19.1 General
5.19.2 Potential risks
5.19.3 Test methods
5.20 N methyl-2-pyrrolidone (NMP)
5.20.1 General
5.20.2 Potential risks
5.20.3 Test methods
5.21 N,N-dimethylacetamide
5.21.1 General
5.21.2 Potential risks
5.21.3 Test methods
5.22 Nickel – Ni
5.23 Nitrosamines
5.23.1 General
5.23.2 Potential risks
5.23.3 Test methods
5.24 Organotins compounds
5.24.1 General
5.24.2 Potential risks
5.24.3 Test methods
5.25 PAHs (Polycyclic aromatic hydrocarbons)
5.25.1 General
5.25.2 Potential risks
5.25.3 Test methods
5.26 Paraphenylene diamine
5.26.1 General
5.26.2 Potential risks
5.26.3 Test methods
5.27 Pesticides
5.27.1 General
5.27.2 Potential risks
5.27.3 Test methods
5.28 Perfluorinated and polyfluorinated chemicals-PFC
5.28.1 Different substances
5.28.2 Potential risks
5.29 pH
5.29.1 General
5.29.2 Potential risks
5.29.3 Test methods
5.30 Phenol
5.30.1 General
5.30.2 Potential risks
5.30.3 Test methods
5.31 Phenyl mercury
5.31.1 General
5.31.2 Potential risks
5.31.3 Test methods
5.32 Phthalates
5.32.1 General
5.32.2 Potential risks
5.32.3 Test methods
5.33 Polychlorophenols
5.33.1 General
5.33.2 Potential risks
5.33.3 Test methods
5.34 Paratertiary butyl phenol formaldehyde (PTBF)
5.34.1 General
5.34.2 Potential risks
5.34.3 Test methods
5.35 Quinoline
5.35.1 General
5.35.2 Potential risks
5.35.3 Test methods
5.36 Thiuram and thiocarbamate
5.36.1 General
5.36.2 Potential risks
5.36.3 Test methods
5.37 Volatile organic compounds (VOC)
5.37.1 General
5.37.2 Potential risks
5.37.3 Test methods
Bibliography
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Foreword
1 Scope
2 Normative references
3 Terms and definitions
4 Presence of chemicals in footwear materials
5 Critical substances potentially present in footwear and footwear components
5.1 Acrylonitrile
5.1.1 General
5.1.2 Potential risks
5.1.3 Test methods
5.2 Alkylphenols and Alkylphenol ethoxylates (NP, OP, NPEO, OPEO)
5.2.1 General
5.2.2 Potential risks
5.2.3 Test methods
5.3 Aromatic amines
5.3.1 General
5.3.2 Potential risks
5.3.3 Test methods
5.4 Benzene
5.4.1 General
5.4.2 Potential risks
5.4.3 Test methods
5.5 Biocides
5.5.1 Orthophenylphenol
5.5.2 2-(thiocyanatomethylthio)-1,3-benzothiazole (TCMTB)
5.5.3 2-octylisothiazol-3(2H)-one (OIT)
5.5.4 4-Chloro-3-methylphenol (CMK)
5.5.5 Triclosan
5.6 Bisphenol
5.6.1 General
5.6.2 Potential risks
5.6.3 Test methods
5.7 Cadmium – Cd
5.8 Chlorinated paraffins
5.8.1 General
5.8.2 Potential risks
5.8.3 Test methods
5.9 Chlorobenzenes and chlorotoluenes
5.9.1 General
5.9.2 Potential risks
5.9.3 Test methods
5.10 Chromium and Chromium VI
5.11 Colophony
5.11.1 General
5.11.2 Potential risks
5.11.3 Test methods
5.12 Dimethylformamide
5.12.1 General
5.12.2 Potential risks
5.12.3 Test methods
5.13 Dimethylfumarate (DMFu)
5.13.1 General
5.13.2 Potential risks
5.13.3 Test methods
5.14 Disperses dyes
5.14.1 General
5.14.2 Potential risks
5.14.3 Test methods
5.15 Flame retardants
5.15.1 General
5.15.2 Potential risks
5.15.3 Test methods
5.16 Formaldehyde
5.16.1 General
5.16.2 Potential risks
5.16.3 Test methods
5.17 Heavy metals
5.17.1 General
5.17.2 List of heavy metals
5.17.3 Potential risks
5.17.4 Test methods
5.17.5 Special cases
5.18 Mercaptobenzothiazole
5.18.1 General
5.18.2 Potential risks
5.18.3 Test methods
5.19 N-ethylphenylamine
5.19.1 General
5.19.2 Potential risks
5.19.3 Test methods
5.20 N methyl-2-pyrrolidone (NMP)
5.20.1 General
5.20.2 Potential risks
5.20.3 Test methods
5.21 N,N-dimethylacetamide
5.21.1 General
5.21.2 Potential risks
5.21.3 Test methods
5.22 Nickel – Ni
5.23 Nitrosamines
5.23.1 General
5.23.2 Potential risks
5.23.3 Test methods
5.24 Organotins compounds
5.24.1 General
5.24.2 Potential risks
5.24.3 Test methods
5.25 PAHs (Polycyclic aromatic hydrocarbons)
5.25.1 General
5.25.2 Potential risks
5.25.3 Test methods
5.26 Paraphenylene diamine
5.26.1 General
5.26.2 Potential risks
5.26.3 Test methods
5.27 Pesticides
5.27.1 General
5.27.2 Potential risks
5.27.3 Test methods
5.28 Perfluorinated and polyfluorinated chemicals-PFC
5.28.1 Different substances
5.28.2 Potential risks
5.29 pH
5.29.1 General
5.29.2 Potential risks
5.29.3 Test methods
5.30 Phenol
5.30.1 General
5.30.2 Potential risks
5.30.3 Test methods
5.31 Phenyl mercury
5.31.1 General
5.31.2 Potential risks
5.31.3 Test methods
5.32 Phthalates
5.32.1 General
5.32.2 Potential risks
5.32.3 Test methods
5.33 Polychlorophenols
5.33.1 General
5.33.2 Potential risks
5.33.3 Test methods
5.34 Paratertiary butyl phenol formaldehyde (PTBF)
5.34.1 General
5.34.2 Potential risks
5.34.3 Test methods
5.35 Quinoline
5.35.1 General
5.35.2 Potential risks
5.35.3 Test methods
5.36 Thiuram and thiocarbamate
5.36.1 General
5.36.2 Potential risks
5.36.3 Test methods
5.37 Volatile organic compounds (VOC)
5.37.1 General
5.37.2 Potential risks
5.37.3 Test methods
Bibliography