ISO 4787:2021
Laboratory glass and plastic ware — Volumetric instruments — Methods for testing of capacity and for use
This document provides methods for the testing, calibration and use of volumetric instruments made from glass and plastic in order to obtain the best accuracy in use.
NOTE Testing is the process by which the conformity of the individual volumetric instrument with the appropriate standard is determined, resulting in the determination of its error of measurement at one or more points.
This document is applicable to volumetric instruments with nominal capacities in the range of 100 µl to 10 000 ml. These include single-volume pipettes (see ISO 648), graduated pipettes (see ISO 835), burettes (see ISO 385), volumetric flasks (see ISO 1042 and ISO 5215), and graduated measuring cylinders (see ISO 4788 and ISO 6706).
The methods are not intended for testing of volumetric instruments with capacities below 100 µl such as micro-glassware.
This document does not deal specifically with pycnometers as specified in ISO 3507. However, the procedures specified for the determination of volume of glassware can, for the most part, also be followed for the determination of a pycnometer volume. For some types of pycnometers, special handling can be necessary.
Foreword
Introduction
1 Scope
2 Normative references
3 Terms and definitions
4 Principle
5 Volume and reference temperature
5.1 Unit of volume
5.2 Reference temperature
6 Apparatus and calibration liquid
6.1 Balance
6.2 Measurement devices
6.3 Calibration liquid
6.4 Receiving vessel
7 Factors affecting the accuracy of volumetric instruments
7.1 General
7.2 Temperature
7.2.1 Temperature of the volumetric instrument
7.2.2 Temperature of calibration liquid
7.3 Cleanliness of surface
7.4 Conditions of used volumetric instruments
7.5 Delivery time and waiting time
8 Setting the meniscus
8.1 General
8.2 Setting the meniscus
8.2.1 Meniscus of transparent liquids
8.2.2 Meniscus of opaque liquids
9 Calibration procedure
9.1 General
9.2 Test room
9.3 Filling and delivery
9.3.1 Volumetric flasks and measuring cylinders
9.3.2 Pipettes adjusted to deliver
9.3.3 Pipettes adjusted to contain
9.3.4 Burettes adjusted to deliver
9.3.5 Pycnometers
9.4 Weighing
9.5 Volume and uncertainty calculation
10 Procedure for use
10.1 General
10.2 Volumetric flasks (in accordance with ISO 1042 or ISO 5215)
10.3 Measuring cylinders (in accordance with ISO 4788 or ISO 6706)
10.4 Burettes (in accordance with ISO 385)
10.5 Pipettes
10.5.1 Pipettes adjusted to deliver (see ISO 648 and ISO 835, or other pipettes, e.g. plastic ones)
10.5.2 Pipettes adjusted to contain
10.6 Pycnometers
Annex A (informative) Cleaning of volumetric glassware
Annex B (informative) Cleaning of volumetric plasticware
Annex C (normative) Calculation formulae and tables
Annex D (informative) Coefficient of cubic thermal expansion
Annex E (informative) Uncertainty estimation and repeatability calculation
Bibliography
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Foreword
Introduction
1 Scope
2 Normative references
3 Terms and definitions
4 Principle
5 Volume and reference temperature
5.1 Unit of volume
5.2 Reference temperature
6 Apparatus and calibration liquid
6.1 Balance
6.2 Measurement devices
6.3 Calibration liquid
6.4 Receiving vessel
7 Factors affecting the accuracy of volumetric instruments
7.1 General
7.2 Temperature
7.2.1 Temperature of the volumetric instrument
7.2.2 Temperature of calibration liquid
7.3 Cleanliness of surface
7.4 Conditions of used volumetric instruments
7.5 Delivery time and waiting time
8 Setting the meniscus
8.1 General
8.2 Setting the meniscus
8.2.1 Meniscus of transparent liquids
8.2.2 Meniscus of opaque liquids
9 Calibration procedure
9.1 General
9.2 Test room
9.3 Filling and delivery
9.3.1 Volumetric flasks and measuring cylinders
9.3.2 Pipettes adjusted to deliver
9.3.3 Pipettes adjusted to contain
9.3.4 Burettes adjusted to deliver
9.3.5 Pycnometers
9.4 Weighing
9.5 Volume and uncertainty calculation
10 Procedure for use
10.1 General
10.2 Volumetric flasks (in accordance with ISO 1042 or ISO 5215)
10.3 Measuring cylinders (in accordance with ISO 4788 or ISO 6706)
10.4 Burettes (in accordance with ISO 385)
10.5 Pipettes
10.5.1 Pipettes adjusted to deliver (see ISO 648 and ISO 835, or other pipettes, e.g. plastic ones)
10.5.2 Pipettes adjusted to contain
10.6 Pycnometers
Annex A (informative) Cleaning of volumetric glassware
Annex B (informative) Cleaning of volumetric plasticware
Annex C (normative) Calculation formulae and tables
Annex D (informative) Coefficient of cubic thermal expansion
Annex E (informative) Uncertainty estimation and repeatability calculation
Bibliography