AS/NZS ISO 8124.5:2020
Safety of toys, Part 5: Chemical toys (sets) other than experimental sets
Objective of this Standard is to specify requirements and test methods for the substances and materials used in chemical toys (sets) other than experimental sets. These substances and mixtures are - those classified as dangerous by the Globally Harmonized System of Classification and Labelling of Chemicals (GHS); substances and mixtures which in excessive amounts could harm the health of the children using them and which are not classified as dangerous by the GHS; and any other chemical substance(s) and mixture(s) delivered with the chemical toy. Additionally, requirements are specified for markings, warnings, safety rules, contents lists, instructions for use and first aid information. Standard applies to - plaster of Paris (gypsum) moulding sets; oven-hardening plasticised PVC modelling clay sets; polystyrene granules sets; embedding sets; and adhesives, paints, lacquers, varnishes, thinners and cleaning agents (solvents) supplied or recommended in model sets. Standard is identical with, and has been reproduced from, ISO 8124-11:2019, Safety of toys - Part 11: Chemical toys (sets) other than experimental sets.
AS/NZS ISO 8124.5:2020 Safety of toys Chemical toys (sets) other than experimental sets
Preface
Foreword
Introduction
1 Scope
2 Normative references
3 Terms and definitions
4 Plaster of Paris (gypsum) moulding sets
4.1 Marking
4.2 First aid information
4.3 Safety rules
5 Oven-hardening plasticised PVC modelling clay sets
5.1 Chemical substances
5.2 Marking
5.3 First aid information
5.4 Safety rules
6 Moulding sets
6.1 Polystyrene granules sets
6.1.1 Chemical substances
6.1.2 Marking
6.1.3 First aid information
6.1.4 Safety rules
6.2 Embedding sets
6.2.1 General
6.2.2 Packaging
6.2.3 Marking
6.2.4 First aid information
6.2.5 Safety rules
7 Adhesives, paints, lacquers, varnishes, thinners and cleaning agents (solvents) supplied or recommended in model sets
7.1 General
7.2 Adhesives
7.2.1 Water-based adhesives
7.2.2 Solvent-based adhesives
7.3 Water-based paints or lacquers
7.3.1 General
7.3.2 Packaging
7.3.3 Marking
7.3.4 First aid information
7.3.5 Safety rules
7.4 Solvent-based paints, lacquers, thinners and cleaning solvents
7.4.1 General
7.4.2 Packaging
7.4.3 Marking
7.4.4 First aid information
7.4.5 Safety rules
8 Marking
8.1 General
8.2 Marking of the primary packaging
8.2.1 General
8.2.2 Manufacturer’s identification
8.2.3 Warning phrases
8.3 Marking of individual containers and any packaging
9 Instructions for use
9.1 General
9.2 Contents list
9.3 Advice for adult supervision
9.4 Safety rules
9.5 Instructions for carrying out the activities
9.6 Spills and disposal of chemicals
10 Test methods
10.1 General
10.2 Determination of plasticisers in oven-hardening polyvinyl chloride (PVC) modelling clay sets
10.2.1 Principle
10.2.2 Standards and reagents
10.2.3 Apparatus
10.2.4 Preparation of standard solutions
10.2.5 Sampling
10.2.6 Sample preparation
10.2.7 Procedure
10.2.8 Evaluation of results
10.2.9 Test report
10.3 Determination of the emission of benzene, toluene and xylenes from oven-hardening plasticised PVC modelling clay sets and polystyrene granules sets
10.3.1 Principle
10.3.2 Standards and reagents
10.3.3 Apparatus
10.3.4 Preparation of standard solutions
10.3.5 Sampling
10.3.6 Sample preparation
10.3.7 Procedure
10.3.8 Evaluation of results
10.3.9 Test report
10.3.10 Critical control points
10.4 Determination of styrene content in polystyrene granules
10.4.1 Principle
10.4.2 Standards and reagents
10.4.3 Apparatus
10.4.4 Preparation of standard solutions
10.4.5 Sampling
10.4.6 Sample preparation
10.4.7 Procedure
10.4.8 Evaluation of results
10.4.9 Test report
10.5 Determination of organic solvents
10.5.1 General
10.5.2 Principle
10.5.3 Standards and reagents
10.5.4 Apparatus
10.5.5 Preparation of the standard solutions
10.5.6 Sampling
10.5.7 Sample preparation
10.5.8 Procedure
10.5.9 Evaluation of results
10.5.10 Test report
10.6 Combined approach for the determination of plasticisers in solvent-based adhesives and in solvent-based paints or lacquers, film-forming agents in paints and lacquers and modifiers in solvent-based paints or lacquers
10.6.1 Principle
10.6.2 Determination of total extract
10.6.3 Identification of nitrocellulose
10.6.4 Determination of plasticisers
10.6.5 Determination of film-forming agents
10.6.6 Determination of the modifiers
10.6.7 Test report
Annex A (normative) Environmental, health and safety precautions for using the methods of analysis
Annex B (informative) Organic solvents
Annex C (informative) Validation of test methods
Annex D (informative) Rationale
Bibliography
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AS/NZS ISO 8124.5:2020 Safety of toys Chemical toys (sets) other than experimental sets
Preface
Foreword
Introduction
1 Scope
2 Normative references
3 Terms and definitions
4 Plaster of Paris (gypsum) moulding sets
4.1 Marking
4.2 First aid information
4.3 Safety rules
5 Oven-hardening plasticised PVC modelling clay sets
5.1 Chemical substances
5.2 Marking
5.3 First aid information
5.4 Safety rules
6 Moulding sets
6.1 Polystyrene granules sets
6.1.1 Chemical substances
6.1.2 Marking
6.1.3 First aid information
6.1.4 Safety rules
6.2 Embedding sets
6.2.1 General
6.2.2 Packaging
6.2.3 Marking
6.2.4 First aid information
6.2.5 Safety rules
7 Adhesives, paints, lacquers, varnishes, thinners and cleaning agents (solvents) supplied or recommended in model sets
7.1 General
7.2 Adhesives
7.2.1 Water-based adhesives
7.2.2 Solvent-based adhesives
7.3 Water-based paints or lacquers
7.3.1 General
7.3.2 Packaging
7.3.3 Marking
7.3.4 First aid information
7.3.5 Safety rules
7.4 Solvent-based paints, lacquers, thinners and cleaning solvents
7.4.1 General
7.4.2 Packaging
7.4.3 Marking
7.4.4 First aid information
7.4.5 Safety rules
8 Marking
8.1 General
8.2 Marking of the primary packaging
8.2.1 General
8.2.2 Manufacturer’s identification
8.2.3 Warning phrases
8.3 Marking of individual containers and any packaging
9 Instructions for use
9.1 General
9.2 Contents list
9.3 Advice for adult supervision
9.4 Safety rules
9.5 Instructions for carrying out the activities
9.6 Spills and disposal of chemicals
10 Test methods
10.1 General
10.2 Determination of plasticisers in oven-hardening polyvinyl chloride (PVC) modelling clay sets
10.2.1 Principle
10.2.2 Standards and reagents
10.2.3 Apparatus
10.2.4 Preparation of standard solutions
10.2.5 Sampling
10.2.6 Sample preparation
10.2.7 Procedure
10.2.8 Evaluation of results
10.2.9 Test report
10.3 Determination of the emission of benzene, toluene and xylenes from oven-hardening plasticised PVC modelling clay sets and polystyrene granules sets
10.3.1 Principle
10.3.2 Standards and reagents
10.3.3 Apparatus
10.3.4 Preparation of standard solutions
10.3.5 Sampling
10.3.6 Sample preparation
10.3.7 Procedure
10.3.8 Evaluation of results
10.3.9 Test report
10.3.10 Critical control points
10.4 Determination of styrene content in polystyrene granules
10.4.1 Principle
10.4.2 Standards and reagents
10.4.3 Apparatus
10.4.4 Preparation of standard solutions
10.4.5 Sampling
10.4.6 Sample preparation
10.4.7 Procedure
10.4.8 Evaluation of results
10.4.9 Test report
10.5 Determination of organic solvents
10.5.1 General
10.5.2 Principle
10.5.3 Standards and reagents
10.5.4 Apparatus
10.5.5 Preparation of the standard solutions
10.5.6 Sampling
10.5.7 Sample preparation
10.5.8 Procedure
10.5.9 Evaluation of results
10.5.10 Test report
10.6 Combined approach for the determination of plasticisers in solvent-based adhesives and in solvent-based paints or lacquers, film-forming agents in paints and lacquers and modifiers in solvent-based paints or lacquers
10.6.1 Principle
10.6.2 Determination of total extract
10.6.3 Identification of nitrocellulose
10.6.4 Determination of plasticisers
10.6.5 Determination of film-forming agents
10.6.6 Determination of the modifiers
10.6.7 Test report
Annex A (normative) Environmental, health and safety precautions for using the methods of analysis
Annex B (informative) Organic solvents
Annex C (informative) Validation of test methods
Annex D (informative) Rationale
Bibliography